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A device is necessary to obtain VPaK conditions inside the reaction vessel. The parameter must change homogeneously and coherently with the modulating function and without altering any other factors important for the reaction or its analytical monitoring. The parameter can change in a vessel being part of the analytical instrument, for example, an ultraviolet visible (UV Vis) spectrophotometric cell [39, 41, 45, 14, 47, 48], an infrared (IR) cell [42, 46], or a uorometer cell [45, 51], or a polarimetric tube [27, 49]. It can change in a reactor vessel where the analytical signal can be read in some way, for example using an optical ber cell for spectrophotometry [52 54] or a conductometric cell [16, 34, 40]. Another possibility is to transport the solution from the reaction vessel to the analytical instrument by a peristaltic pump [38]. When altenative ways are not practicable, samples can be taken at suitable time intervals and analyzed apart [29, 31, 35, 39, 43, 50]. Any system satisfying the conditions cited above can be useful as VPaK devices. For VTK programmable thermostatic baths (with the possibility of external circulation) and temperature programmers using the Peltier effect are very convenient. It is always necessary to homogenize the temperature and the composition of the solution with good stirring, monitoring the temperature by measuring it inside the reaction vessel, possibly memorizing it in a computer. A linear increasing temperature is suf cient and it is enough easy to realize, but other modulating functions, for various reasons, have been tested [33, 35, 47]. However, for future particular applications, the use of a computer with suitable software can easily generate T(t) pro les having various shapes.

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The authors concluded that for a collimated or weakly converging pump beam, corresponding to a case when the pump intensity is subject to strong variations along the internal path of the nonlinear medium, a single pulse or train of pulses with power exceeding that of the pump might appear in backward SBS Pressurized gases were mainly used in early SBS pulse compressor experiments At the time, these gases were virtually the only media that afforded very low absorption over relatively long path lengths (up to several meters) typical for SBS compressors used for compression of pulses with duration of tens of nanoseconds Puri ed liquid nonlinear materials were later developed, investigated, and applied as part of research into SBS pulse compression and its application in laser systems Reference 5 describes an investigation in which a 200-mJ, 20-ns pulse from an Nd:YAG laser-based system was directed into a 1.

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P1: KOA WY050-01 WY050-Ulick-v4 September 23, 2004 0:29

r ( C 1 ~ 1 ) r(C2,1)

140 120 N+F Avg box count: 70.582

3-m tapered waveguide lled with pressurized methane at 130 atm The cell s length did not match the pulse duration in this situation Consequently, the backre ected Stokes pulse had a sharp leading spike followed by a relatively long tail This partially compressed pulse was directed back to the same cell after experiencing a corresponding delay As a response of this input, a second SBS was observed with a pulse width of 2 + 05 ns In our opinion, this was not true second Stokes pulse compression, but rather its backscattering which made the 2-ns spike of the partially compressed rst Stokes pulse more pronounced, through saturated ampli cation of the lasing medium In Ref 7 it was experimentally demonstrated that SBS in an argon cell with a length of l .

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In high energy accelerators, there are two sources of linear coupling insofar as single particle motion is concerned: rotated (or skew) quadrupole fields arising from alignment errors, and occasionally, solenoidal fields associated with high energy physics experiments. Here we concentrate on the first, though the techniques readily admit of generalization. We apply the method of variation of parameters used in 4 to the motion in the presence of a single skew quadrupole. In the introduction to this chapter, we wrote down the field of a quadrupole which had rotated about its axis through an angle 4 from its normal orientation. For small 4, the changes in x and y for a particle traversing this rotated quadrupole, in

ctP =2 enables one to compress 20-ns laser pulses to pulses with duration of 1 ns with energy conversion ef ciencies of more than 80% It was found that there exist both an optimal pump energy, Eopt, and an optimal converging angle bopt Dp =F, where Dp is the pumping beam diameter at the entrance of the cell and F is the distance between the entrance and focal planes [10] As a rule, SBS-active liquids possess substantially lower SBS thresholds than do pressurized gases Unfortunately, the threshold for competing processes such as SRS is also lower in most nonlinear liquids than in gases A con guration based upon nonlinear liquids and using a simple SBS compressor generator geometry demonstrated subnanosecond pulse generation while utilizing a weak (less than tens of millijoules) pump.

where Q(x) denotes the pumping rate of a speci c pumping test. That is, for pumping test p, Q(x) is zero for all positions x except for a very small region around xp . Equation (3.1) is to be restricted with respect to the H measurements obtained from all the pumping tests (1 p nq ) such that a suitable heterogeneous eld K(x) can be found. As boundary conditions for (3.1), it is common to divide the boundary of into two disjoint parts: = 1 2 , where on the Dirichlet boundary 1 , the value of H is prescribed: H| whereas on the Neumann boundary

11

It is dif cult to scale liquid SBS compressors beyond 1-J output energy level with a single-cell SBS compressor con guration, due to.

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